// Gas reference · combustible / LPG

Propane
C₃H₈

Simple asphyxiant and mild CNS depressant at high %; NIOSH REL 1000 ppm. flammable (simple asphyxiant).

CAS 74-98-6
UN 1978
IR 3.4 µm
GWP₁₀₀ —
Molecule — drag to rotateC₃H₈ · 44.1 g/mol
geometry: PubChem CID 6334 · CPK colours · drag / touch to rotate
Identifiers for search
NamePropane
FormulaC₃H₈
IUPAC namepropane
CAS number74-98-6
EC number200-827-9
UN number1978 — Propane
Transport class (ADR/RID)2.1 (Flammable Gases)
PubChem CID6334
SynonymsBottled gas, Dimethyl methane, n-Propane, Propyl hydride
Physical & chemical properties
Molar mass44.1 g/mol
Boiling point (1 atm)-42.1 °C
Melting point-187.7 °C
Critical temperature96.8 °C
Critical pressure42.6 bar
Vapour pressure8.367 bar at 20 °C
Gas density2.0098 kg/m³ (0 °C, 1013 mbar)
Relative density (air = 1)1.55
Solubility in water42,4 ml/l at 20 °C
Appearancegas liquefied under pressure, colourless, odourless
Odourodourless
1 ppm at 20 °C1.83 mg/m³
Behaviour with temperature and pressure

Boiling point -42.1 °C at 1 atm: a liquefied gas under its own vapour pressure in cylinders. Critical point 96.8 °C / 42.6 bar: below this temperature it can be stored as a liquid; cylinder pressure then equals the vapour pressure. Vapour pressure ≈ 8.367 bar at 20 °C — this is the pressure inside a cylinder or a switchgear compartment at that temperature, and it rises steeply with temperature (Clausius–Clapeyron). Relative density 1.55 (air = 1): heavier than air — accumulates in pits, cable basements and at floor level; place sensors low. Conversion at 20 °C, 1013 mbar: 1 ppm = 1.83 mg/m³; NDIR reads partial pressure, so readings scale with absolute pressure (value = reading × P/1013) and must be pressure-compensated.

// Extremely flammable gas. Forms hazardous explosive mixtures with air., Only slightly soluble in water., Gas is heavier than air.
Hazards & safety
NFPA 704
4 1 0 SA
health · flammability · instability · special
GHS / CLP pictograms
Flammable pictogram (GHS02)
GHS02 · Flammable
Gas under pressure pictogram (GHS04)
GHS04 · Gas under pressure
Hazard classflammable (simple asphyxiant)
GHS signal wordDanger
CLP classificationFlammable gases, Category 1; H220
Gases under pressure, liquefied gas; H280
Hazard statementsH220: Extremely flammable gas.
H280: Contains gas under pressure; may explode if heated.
Lower / upper explosion limit1.7 vol% / 10.8 vol%
Auto-ignition temperature470 °C · T1 · group IIA
Seveso III named substanceyes
Exposure limits
EU indicative OELV (8 h TWA)no EU IOELV
EU IOELV short-term (15 min)
Germany AGW (TRGS 900)1000 ppm · 1800 mg/m³
Netherlandswettelijke grenswaarde per Arboregeling bijlage XIII — SER grenswaarden database
NIOSH REL (USA)TWA 1000 ppm (1800 mg/m3)
OSHA PEL (USA)TWA 1000 ppm (1800 mg/m3)
IDLH2100 ppm [10%LEL]
// Limits change: always confirm the current national value before setting an alarm. Values above were read from the EU directives / GESTIS / NIOSH pages listed in Sources.
Effect on people

Simple asphyxiant and mild CNS depressant at high %; NIOSH REL 1000 ppm. Main hazard is fire/explosion (LEL 1.7 vol%); 1.5× heavier than air — accumulates at floor level.

GESTIS main toxic effects: Acute: Frostbite following skin contact with the gas which has been let down; central-nervous disturbances; in extreme situations suffocation due to oxygen deficiency Chronic: Dessication of the mucous membranes, cough, gastrointestinal disturbances and functional changes to the heart through high concentrations
Recommended monitoring
Climate & atmosphere
GWP₁₀₀ — IPCC AR6
GWP₁₀₀ — IPCC AR4
GWP used in Reg. (EU) 2024/573not listed
Atmospheric lifetime
Ozone depletion potential0
Main IR absorption band (NDIR)3.4 µm (C–H stretch, 2960 cm⁻¹); 6.8–7.2 µm (CH₂/CH₃ deformation)
Regulation windows
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Sources
  1. https://gestis-database.dguv.de/data?name=010020
  2. https://www.cdc.gov/niosh/npg/npgd0524.html
  3. https://pubchem.ncbi.nlm.nih.gov/compound/6334
  4. IPCC AR6 WG1 Ch.7 Supplementary Material, Table 7.SM.7 (https://www.ipcc.ch/report/ar6/wg1/downloads/report/IPCC_AR6_WGI_Chapter07_SM.pdf)
  5. HITRAN/NIST IR band positions (approximate centre of the strongest band used for NDIR; https://hitran.org, https://webbook.nist.gov)
// Data compiled 2026-09-17 from the listed primary sources; null values were left blank rather than estimated.
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